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钛合金 4

增材制造 2

无氢渗碳 2

海绵钛 2

钛 2

Ni–Ti–Cu–V合金 1

TC4钛合金 1

三态组织 1

人造金红石 1

光纤激光器；被动锁模；可饱和吸收体；二硫化钛 1

关键技术 1

加压浸出 1

动态强度 1

动态硬度 1

双层辉光离子渗金属 1

发展动态 1

可降解镁合金 1

四元合金 1

大块非晶合金，模型铸造，金属材料，结构弛豫 1

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Anodization of titanium alloys for orthopedic applications

Merve İzmir, Batur Ercan

《化学科学与工程前沿（英文）》 2019年第13卷第1期页码 28-45 doi: 10.1007/s11705-018-1759-y

摘要：

In recent years, nanostructured oxide films on titanium alloy surfaces have gained significant interest due to their electrical, catalytic and biological properties. In literature, there is variety of different approaches to fabricate nanostructured oxide films. Among these methods, anodization technique, which allows fine-tuning of oxide film thickness, feature size, topography and chemistry, is one of the most popular approaches to fabricate nanostructured oxide films on titanium alloys, and it has been widely investigated for orthopedic applications. Briefly, anodization is the growth of a controlled oxide film on a metallic component attached to the anode of an electrochemical cell. This review provides an overview of the anodization technique to grow nanostructured oxide films on titanium and titanium alloys and summarizes the interactions between anodized titanium alloy surfaces with cells in terms of cellular adhesion, proliferation and differentiation. It will start with summarizing the mechanism of nanofeatured oxide fabrication on titanium alloys and then switch its focus on the latest findings for anodization of titanium alloys, including the use of fluoride free electrolytes and anodization of 3D titanium foams. The review will also highlight areas requiring further research to successfully translate anodized titanium alloys to clinics for orthopedic applications.

关键词： titanium alloys anodization biocompatibility orthopedics

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钛合金离子渗镀表面处理新进展

张高会,徐　重,张平则,葛洪良,崔玉建,温廷敦,潘俊德

《中国工程科学》 2007年第9卷第11期页码 163-166

摘要：

介绍了钛合金表面加弧辉光离子无氢渗镀碳、双层辉光离子无氢渗碳、双层辉光离子渗铬、渗铜等表面处理的新方法；检测结果显示在钛合金表面均形成了梯度合金层，进一步检测表明，表面渗镀合金层对改善钛合金耐磨、耐蚀和阻燃性均有显著的作用。

关键词：钛合金无氢渗碳抗磨阻燃

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钛——跨入新千年的金属巨人

杨遇春

《中国工程科学》 2002年第4卷第3期页码 21-31

摘要：

介绍了海绵钛提取及钛材生产在20世纪的兴起与发展；论述了钛、钛材、钛合金在国民经济各主要工业部门，特别是在高新技术领域的广泛应用与重要作用；展望了钛工业在新千年的市场前景并提出在我国应给予重点发展和关注的建议。

关键词：钛海绵钛钛材钛工业钛的市场供求

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钛在汽车工业中的应用及降低钛材成本的工艺

杨遇春

《中国工程科学》 2005年第7卷第8期页码 9-17

摘要：

叙述了钛在减轻汽车自重、节约燃油、保护环境、降低噪声、提高汽车性能方面的优势和应用领域及趋势。介绍并评价了几种降低海绵钛与钛材成本的工艺技术。

关键词：钛汽车用钛材钛冶金新工艺

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Temperature effects of shape memory alloys (SMAs) in damage control design of steel portal frames

Xiaoqun LUO, Hanbin GE, Tsutomu USAMI

《结构与土木工程前沿（英文）》 2012年第6卷第4期页码 348-357 doi: 10.1007/s11709-012-0176-4

摘要： The objective of the present study is to analytically investigate temperature effects of an axial-type seismic damper made of shape memory alloys (SMAs) equipped in steel frames. Based on a modified multilinear one dimensional constitutive model of SMAs, two types of SMAs are employed, which have different stress plateau and different stress growth rate with temperature increase. Temperature effects of SMA dampers on seismic performance upgrading are discussed in three aspects: different environment temperatures; rapid loading rate induced heat generation and different SMA fractions. The analysis indicates that the effect of environment temperature should be considered for the SMA damper in steel frames. However, the rapid loading rate induced heat generation has little adverse effect.

关键词： damage control design shape memory alloy temperature effect

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Removal of fluoride from water using titanium-based adsorbents

Zhijian LI, Shubo DENG, Xueying ZHANG, Wei ZHOU, Jun HUANG, Gang YU

《环境科学与工程前沿（英文）》 2010年第4卷第4期页码 414-420 doi: 10.1007/s11783-010-0241-y

摘要： Three adsorbents including TiO , Ti-Ce, and Ti-La hybrid oxides were prepared to remove fluoride from aqueous solution. The Ti-Ce and Ti-La hybrid adsorbents obtained by the hydrolysis-precipitation method had much higher sorption capacity for fluoride than the TiO adsorbent prepared through hydrolysis. Rare earth (Ce and La) oxides and TiO exhibited a synergistic effect in the hybrid adsorbents for fluoride sorption. The sorption equilibrium of fluoride on the three adsorbents was achieved within 4 h, and the pseudo-second-order model described the sorption kinetics well. The sorption isotherms fitted the Langmuir model well, and the adsorption capacities of fluoride on the Ti-Ce and Ti-La adsorbents were about 9.6 and 15.1 mg·g , respectively, at the equilibrium fluoride concentration of 1.0 mg·L , much higher than the 1.7 mg·g on the TiO . The sorption capacities of fluoride on the three adsorbents decreased significantly when the solution pH increased from 3 to 9.5. The electrostatic interaction played an important role in fluoride removal by the three adsorbents, and Fourier transform infrared (FTIR) analysis indicated that the hydroxyl groups on the adsorbent surface were involved in fluoride adsorption.

关键词： fluoride adsorption titanium dioxide titanium-based adsorbent sorption mechanism

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Photocatalytic reduction of carbon dioxide by titanium oxide-based semiconductors to produce fuels

Xi CHEN, Fangming JIN

《能源前沿（英文）》 2019年第13卷第2期页码 207-220 doi: 10.1007/s11708-019-0628-9

摘要： To tackle the crisis of global warming, it is imperative to control and mitigate the atmospheric carbon dioxide level. Photocatalytic reduction of carbon dioxide into solar fuels furnishes a gratifying solution to utilize and reduce carbon dioxide emission and simultaneously generate renewable energy to sustain the societies. So far, titanium oxide-based semiconductors have been the most prevalently adopted catalysts in carbon dioxide photoreduction. This mini-review provides a general summary of the recent progresses in titanium oxide-catalyzed photocatalytic reduction of carbon dioxide. It first illustrates the use of structural engineering as a strategy to adjust and improve the catalytic performances. Then, it describes the introduction of one/two exogenous elements to modify the photocatalytic activity and/or selectivity. Lastly, it discusses multi-component hybrid titanium oxide composites.

关键词： photocatalysis carbon dioxide reduction semiconductors titanium oxide renewable fuels

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The modification of titanium in mesoporous silica for Co-based Fischer–Tropsch catalysts

《化学科学与工程前沿（英文）》 2022年第16卷第8期页码 1224-1236 doi: 10.1007/s11705-022-2139-1

摘要： Ordered SBA-15 mesoporous silica with incorporated titanium was successfully synthesized via a one-pot hydrothermal crystallization method. The characterization including powder X-ray diffraction, Brunauer–Emmett–Teller, transmission electron microscope, temperature-programmed reduction, temperature-programmed desorption, Fourier transform infrared and ultraviolet-visible-near infrared spectrometer was performed to explore the physical and chemical structures of both the supports and the catalysts. The results showed that titanium was successfully incorporated into the mesoporous silica framework with a limited amount of titanium (Si/Ti > 20), and the mesoporous structure was retained. However, the increased titanium content inevitably resulted in the formation of anatase TiO ₂ particles on the support surface. The increased incorporated titanium strengthened the interactions between cobalt species and supports, which was favorable for the cobalt species dispersion, despite the limited cobalt oxide reducibility. The enhanced metal-support interactions were beneficial for the CO/H₂ ratio at the active cobalt sites, which facilitated the formation of more C₅₊ hydrocarbons. This study provides a promising method for support modification with incorporated-heteroatoms for the rational development of Fischer–Tropsch catalysts.

关键词： Fischer–Tropsch synthesis titanium incorporation mesoporous silica metal-support interactions C₅₊ selectivity

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Machinability of damage-tolerant titanium alloy in orthogonal turn-milling

Tao SUN, Lufang QIN, Junming HOU, Yucan FU

《机械工程前沿（英文）》 2020年第15卷第3期页码 504-515 doi: 10.1007/s11465-020-0586-2

摘要： The damage-tolerant titanium alloy TC21 is used extensively in important parts of advanced aircraft because of its high strength and durability. However, cutting TC21 entails problems, such as high cutting temperature, high tool tip stress, rapid tool wear, and difficulty guaranteeing processing quality. Orthogonal turn-milling can be used to solve these problems. In this study, the machinability of TC21 in orthogonal turn-milling is investigated experimentally to optimize the cutting parameters of orthogonal turn-milling and improve the machining efficiency, tool life, and machining quality of TC21. The mechanism of the effect of turn-milling parameters on tool life is discussed, the relationship between each parameter and tool life is analyzed, and the failure process of a TiAlN-coated tool in turn-milling is explored. Experiments are conducted on the integrity of the machined surface (surface roughness, metallographic structure, and work hardening) by turn-milling, and how the parameters influence such integrity is analyzed. Then, reasonable cutting parameters for TC21 in orthogonal turn-milling are recommended. This study provides strong guidance for exploring the machinability of difficult-to-cut-materials in orthogonal turn-milling and improves the applicability of orthogonal turn-milling for such materials.

关键词： orthogonal turn-milling damage-tolerant titanium alloy tool life and failure machined surface integrity machinability

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Effect of triethylamine treatment of titanium silicalite-1 on propylene epoxidation

Juan XU,Yaquan WANG,Wenping FENG,Yi LIN,Shuhai WANG

《化学科学与工程前沿（英文）》 2014年第8卷第4期页码 478-487 doi: 10.1007/s11705-014-1453-7

摘要： Titanium silicalite-1(TS-1) treated with triethylamine (TEA) solution under different conditions was characterized by X-ray powder diffraction (XRD), Fourier-transform infrared spectrum (FTIR), ultraviolet-visible diffuse reflectance spectrum (UV-Vis), nitrogen physical adsorption and desorption, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The characterization results show that many irregular hollows are generated in the TS-1 crystals due to the random dissolution of framework silicon and the volume of the hollow cavities increase with increasing the TEA concentration, and the treatment temperature and time. The modified TS-1 samples improved in varying degrees the catalyst life for the epoxidation of propylene in a fixed-bed reactor probably due to the generation of the hollows to make it easy for the reactants and products to diffuse out of the channels.

关键词： titanium silicalite-1 triethylamine hollow cavity epoxidation of propylene catalyst life

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Flux-free brazing of Mg-containing aluminium alloys by means of cold spraying

BOBZIN Kirsten, ZHAO Lidong, ERNST Felix, RICHARDT Katharina

《机械工程前沿（英文）》 2008年第3卷第4期页码 355-359 doi: 10.1007/s11465-008-0055-9

摘要： In the present study, AlSi12 and AlSi10Cu4 were deposited onto Mg-containing aluminium alloys 6063 and 5754 by cold spraying. The influences of the two brazing alloys and spray parameters on coating formation were investigated. The microstructure of the coatings was characterized. Some coated samples were heat-treated at 590°C and 560°C in air to investigate the effect of the rupture of oxide scales on the diffusion of elements during heat-treatment. Some coated samples were brazed under argon atmosphere without any fluxes. The results show that AlSi12 had much better deposition behaviour than AlSi10Cu4. Due to the rupture of oxide scales, Cu and Si diffused into the substrate and a metallurgical bond formed between the brazing alloys and the substrates during heat-treatment. The coated samples could be brazed without any fluxes. Because the oxide scales prevented the formation of a metallurgical bond locally, the brazed samples had relatively low shear strengths of up to 43 MPa.

关键词： diffusion metallurgical substrate Mg-containing aluminium spraying

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Fatigue crack initiation of magnesium alloys under elastic stress amplitudes: A review

B. J. WANG, D. K. XU, S. D. WANG, E. H. HAN

《机械工程前沿（英文）》 2019年第14卷第1期页码 113-127 doi: 10.1007/s11465-018-0482-1

摘要： The most advantageous property of magnesium (Mg) alloys is their density, which is lower compared with traditional metallic materials. Mg alloys, considered the lightest metallic structural material among others, have great potential for applications as secondary load components in the transportation and aerospace industries. The fatigue evaluation of Mg alloys under elastic stress amplitudes is very important in ensuring their service safety and reliability. Given their hexagonal close packed structure, the fatigue crack initiation of Mg and its alloys is closely related to the deformation mechanisms of twinning and basal slips. However, for Mg alloys with shrinkage porosities and inclusions, fatigue cracks will preferentially initiate at these defects, remarkably reducing the fatigue lifetime. In this paper, some fundamental aspects about the fatigue crack initiation mechanisms of Mg alloys are reviewed, including the 3 followings: 1) Fatigue crack initiation of as-cast Mg alloys, 2) influence of microstructure on fatigue crack initiation of wrought Mg alloys, and 3) the effect of heat treatment on fatigue initiation mechanisms. Moreover, some unresolved issues and future target on the fatigue crack initiation mechanism of Mg alloys are also described.

关键词： Mg alloys fatigue behavior microstructure crack initiation deformation mechanism

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Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 24-31 doi: 10.1007/s11705-017-1669-4

摘要： We have successfully prepared a series of Pd-Ni/TiO catalysts by a one-step impregnation-reduction method. Among these catalysts with different compositions of Ni and Pd, the one with the Ni:Pd ratio of 2.95 showed the best activity. Small monodispersed Pd-Ni bimetallic nanoparticles were loaded on the surface of titanium oxide nanopowder as confirmed with TEM and EDS mapping. The XPS analysis demonstrated that Pd exists as 31% Pd(II) species and 69% Pd(0) species and all nickel is Ni(II). The prepared Pd-Ni/TiO exhibited enhanced catalytic activity compared to an equal amount of Pd/TiO for Suzuki-Miyaura reactions together with excellent applicability and reusability.

关键词： Pd-Ni bimetallic nanoparticles nanocatalysis Suzuki-Miyaura reaction titanium oxide

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Effect of sodium ions in synthesis of titanium silicalite-1 on its catalytic performance for cyclohexanone

Pengxu YAO,Yaquan WANG,Teng ZHANG,Shuhai WANG,Xiaoxue WU

《化学科学与工程前沿（英文）》 2014年第8卷第2期页码 149-155 doi: 10.1007/s11705-014-1409-y

摘要： Titanium silicalite-1 (TS-1) has been hydrothermally synthesized with tetrapropylammonium hydroxide (TPAOH) as the template in the presence of various amounts of Na , characterized by inductively coupled plasma, X-ray diffraction, scanning electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and ultro-violet-visible spectroscopy and studied in cyclohexanone ammoximation. The characterization results show that with the increase of Na concentration in the synthesis, both the crystal sizes of TS-1and extra framework Ti increase but framework Ti decreases. The addition of Na below 3 mol-% of TPAOH in the synthesis does not influence the catalytic properties with above 98% conversion of cyclohexanone and 99.5% selectivity to cyclohexanone oxime. However, at the concentrations of Na ≥3 mol-% of TPAOH in the synthesis, the catalysts are deactivated faster with the increase of Na addition, which can be attributed to more high molecular weight byproducts deposited in the large TS-1 particles and the loss of the frame-work titanium. The results of this work are of great importance for the industry.

关键词： extra framework Ti cyclohexanone ammoximation titanium silicalite-1 sodium ion crystal size

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大块非晶合金：历史发展和当前研究 Review

Akihisa Inoue

《工程（英文）》 2015年第1卷第2期页码 185-191 doi: 10.15302/J-ENG-2015038

摘要：

通过关注采用传统模型铸造方法合成首批大块非晶合金的触发点，本文论述了大块非晶合金的当前研究进展情况。该综述涵盖大块非晶合金的背景、发现、特点和应用以及近期与其相关的研究主题。由于其性质独特，非晶形成能力高且成本低廉，大块非晶合金 ( 尤其是铁基大块非晶合金) 的应用范围正逐步扩大。在不久的将来，大块非晶合金在工程领域的重要性预计将稳步提高，预期将上述创新型金属材料用于基础科学研究的热度仍将持续。

关键词：大块非晶合金，模型铸造，金属材料，结构弛豫

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标题作者时间类型操作

Anodization of titanium alloys for orthopedic applications

Merve İzmir, Batur Ercan

期刊论文

钛合金离子渗镀表面处理新进展

张高会,徐　重,张平则,葛洪良,崔玉建,温廷敦,潘俊德

期刊论文

钛——跨入新千年的金属巨人

杨遇春

期刊论文